李忠曙

副教授

辦公電話

+86-20-84113994

電子郵件

lizhsh6@mail.sysu.edu.cn

基本情況

姓名：李忠曙

性别：男

出生年月：1983-09

籍貫：湖南

職位：副教授，碩士生導師。

聯系方式

電話：+86-20-84113994

傳真：+86-20-84113994

郵箱：lizhsh6@mail.sysu.edu.cn

通訊地址：廣州市新港西路135号太阳集团1088vip豐盛堂C313

郵編：510275

教育經曆

2009.07-2013.10：蘇黎士聯邦理工大學（瑞士），有機化學，理學博士

2006.09-2009.06：東南大學，材料科學與組織工程，碩士

2002.09-2006.06：湖南工程學院，化學工程與工藝，學士

工作經曆

2019.05－至今副教授，太阳集团1088vip

2016.07‐2019.04：特聘副研究員，太阳集团1088vip

2014.07‐2016.06：博士後，太阳集团1088vip（導師：蘇成勇教授）

2013.10‐2014.09：博士後，蘇黎士聯邦理工大學（瑞士）（導師：Prof. Hansjörg Grützmacher）

科研方向

有機磷化學，主族元素化學，自由基化學，金屬有機化學

科研項目

1. 國家自然科學基金（青年科學基金項目）：以膦烯酮為模闆并用氮雜環卡賓來催化的合成磷雜環的研究；批号：21603280；李忠曙（主持）；20萬元；起止時間2017.01-2019.12。

2. 高校基本科研業務費（青年教師培育項目）：基于新穎膦雜環配體的金屬配合物的合成及其熒光性質研究；批号：17lgpy78；李忠曙（主持）；15萬元；起止時間2017.01-2019.12。

3. 中國博士後科學基金面上第57批二等資助：新穎含磷光引發劑的開發及其在材料科學上的應用；批号，2015M572397；李忠曙（主持）；5萬元；起止時間2015.05-2016.10。

4. 元素有機國家重點實驗室（南開大學）開放基金項目：單線态、雙線态和三線态碳化膦自由基：合成、結構和反應活性研究，李忠曙（主持）；3萬元；起止時間2019.01-2019.12。

5. 國家自然科學基金（重大國際（地區）合作研究項目）：基于動态化學作用的配位超分子自組裝與功能化研究；批号：21720102007；李忠曙（參與，排名第五）；241萬元；起止時間：2018.01-2022.12。

6. 高校基本科研業務費（重大項目培育和新興交叉學科培育計劃項目）：功能活性配位超分子的動态組裝、調控與應用；批号：17lgjc12；李忠曙（參與，排名第五）；30萬元；起止時間：2017.04-2018.12。

論著一覽

22 X. Chen,# L. L. Liu,# S. Liu, H. Grützmacher, Z. Li,* A Room Temperature Stable Distonic Radical Cation, Angew. Chem. Int. Ed. 2020, accepted, https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202011677

21 X. Zhang,# X. Chen,# H. Zhai, S. Liu, C. Hu, L. L. Liu,* S. Wang, Z. Li,* Facile Addition of E–H bonds to a Dicarbondiphosphide, Dalton Trans. 2020, 49, 6384–6390.

20 Z. Li,* X. Chen, L. L. Liu, M. T. Scharnhölz, H. Grützmacher,* N-Heterocyclic Carbenes Stabilized Dicarbondiphosphides: Strong Neutral Four-Membered Heterocyclic 6π-electron Donors, Angew. Chem. Int. Ed. 2020, 59, 4288–4293; Angew. Chem. 2020, 132, 4318–4323. X-Mol: http://notice.x-mol.com/news/306314

19 Z. Li, J. E. Borger,* F. Müller, J. R. Harmer, C.-Y. Su, H. Grützmacher,* Phosphanyl Cyanophosphide Salts: Versatile PCN Building Blocks, Angew. Chem. Int. Ed. 2019, 58, 11429–11433; Angew. Chem. 2019, 131, 11551–11555 (Inside Cover).

18 X. Chen, Z. Li,* G. Frenking,* I. Fernández, L. Zhao, H. Grützmacher,* Bent Phosphaallenes With “Hidden” Lone Pairs as Ligands, Chem. Eur. J. 2019, 25, 7912–7920 (Hot Paper).

17 Y. Hou, Z. Li,* Y. Li, P. Liu, C.-Y. Su,* F. Puschmann, H. Grützmacher,* Making the Unconventional μ2–P Bridging Binding Mode More Conventional in Phosphinine Complexes, Chem. Sci. 2019, 10, 3168–3180 (Inside Cover).

16 X. Chen, A. Hinz, J. R. Harmer,* Z. Li,* Metastable Phosphorus Neutral Monoradical: A Key Intermediate in the Bicyclic Cage Formation, Dalton Trans. 2019, 48, 2549–2553.

15 Y. Li, Z. Li,* Y. Hou, Y.-N. Fan, C.-Y. Su,* Photoluminescent Phosphinine Cu(I) Halide Complexes: Temperature Dependence of the Photophysical Properties and Applications as a Molecular Thermometer, Inorg. Chem., 2018, 27, 13235–13245.

14 X. Chen, Z. Li,* H. Grützmacher,* Multi-dentate Phosphanyl Phosphinines: Synthsis and Properties, Chem. Eur. J. 2018, 24, 8432–8437.

13 Z. Li,* Y. Hou, Y. Li, A. Hinz,* X. Chen,* Biradicaloid and Zwitterion Reactivity of Dicarbondiphosphide Stabilized with N-Heterocyclic Carbenes, Chem. Eur. J. 2018, 24, 4849–4855; 4738 (Inside Cover).

12 Z. Li, Y. Hou, Y. Li, A. Hinz, J. R. Harmer, C.-Y. Su,* H. Grützmacher,* L3C3P3: Tricarbontriphosphide Cage Radicals and Cations Stabilized by Cyclic(alkyl)(amino)carbenes, Angew. Chem. Int. Ed., 2018, 57, 198–202.

11 A. Beil, G. Müller, d. Käser, B. Hattendorf, Z. Li, f. Krumeich, A. Rosenthal, V. K. Rana, H. Schönberg, Z. Benkö, H. Grützmacher,* Bismesitoylphosphinic Acid (BAPO-OH): A Ligand for Copper Complexes and Four-Electron Photoreductant for the Preparation of Copper Nanomaterials, Angew. Chem. Int. Ed., 2018, 57, 7697–7702.

10 Z. Li, X. Chen, D. M. Andrada, G. Frenking,* Z. Benkö, Y. Li, J. R. Harmer, C.-Y. Su,* H. Grützmacher,* (L)2C2P2: Dicarbondiphosphide Stabilized by N-Heterocyclic Carbenes or Cyclic Diamido Carbenes, Angew. Chem. Int. Ed., 2017, 56, 5744–5749.

9 R. Suter, Y. Mei, M. Baker, Z. Benkő, Z. Li, H. Grützmacher, 2,4,6-Tri(hydroxy)-1,3,5-triphosphinine, P3C3(OH)3: The Phosphorus Analogue of Cyanuric Acid, Angew. Chem. Int. Ed., 2017, 56, 1356–1360.

8 Z. Li,* X. Chen, Y. Li, C.-Y. Su,* H. Grützmacher,* N-Heterocyclic carbene phosphaketene adducts as precursors to carbene-phosphinidene adducts and a rearranged pi-system, Chem. Commun., 2016, 52, 11343–11346. (Inside Cover)

7 Z. Li, X. Chen, Z. Benkö, L. Liu, D. A. Ruiz, J. L. Peltier, G. Bertrand,* C.-Y. Su,* H. Grützmacher,* N-heterocyclic carbenes as promotors for the rearrangement of phosphaketenes to phosphaheteroallenes: A case study for OCP to OPC constitutional isomerism, Angew. Chem. Int. Ed. 2016, 55, 6018–6022.

6 X. Chen, Z. Li,* Y. Fan, H. Grützmacher,* Synthesis and Photoluminescenece properties of Cu(I) complexes with chelating phosphinito phosphinene ligands, Euro. J. Inorg. Chem. 2016, 5, 633–638. (Back Cover)

5 Z. Li, X. Chen, M. Bergeler, M. Reiher, C.-Y. Su, H. Grützmacher,* A stable phosphanyl phosphaketene and its reactivity, Dalton Trans. 2015, 44, 6431–6438.

4 X. Chen, S. Alidori, F. F. Pushmann, G. S. Quinones, Z. Benkö, Z. Li, G. Becher, H. F. Grützmacher, H. Grützmacher, Sodium phosphathynolate as a building block for heterocycles, Angew. Chem. Int. Ed., 2014, 53, 1641–1645.

3 Z. Li, E. P. A. Couzijn, X. Zhang, A quantitative Study of Intrinsic Non-covalent Interactions within Complexes of α-Cyclodextrin and Benzoate Derivatives, Chem. Commun. 2012, 48, 9864–9866.

2 Z. Li, E. P. A. Couzijn, X. Zhang, Intrinsic Properties of α-Cyclodextrin Complexes with Benzoate Derivatives in the Gas Phase: An Experimental and Theoretical Study, J. Phys. Chem. B. 2012, 116, 943–950.

1 Y. Li, Z. Li, T. Xiong, Q. Zhang, X. Zhang, Copper-Catalyzed Selective Benzylic C-O Cyclization of N-o-Tolylbenzamides: Synthesis of 4H-3,1-Benzoxazines, Org. Lett. 2012, 14, 3522–3525.

發明專利

李忠曙，李雅奇，蘇成勇，一種銅（I）膦雜環配合物及其制備方法和應用，中國發明專利，專利申請日期：2017年08月29日，授權日期：2019年11月12日，專利号：ZL 2017 1 0756684.1