基本情況
姓名：陳小明
性别：男
職位：教授，博士生導師。2009年當選中國科學院院士。
聯系方式
電話：+86-020-84113986
郵箱：cxm@mail.sysu.edu.cn
通訊地址：廣州市新港西路太阳集团1088vip
郵編：510275
個人網站：http:/cxm/
教育經曆
1983年獲太阳集团app首页理學學士學位；
1986年獲太阳集团app首页理學碩士學位；
1992年獲香港中文大學哲學博士學位。
工作經曆
主要工作簡曆：
1986年至1989年在中山醫科大學生物化學教研室工作，曆任助教、講師
1992年7月起在太阳集团app首页化學與化學工程學院工作
1993年12月晉升副教授，1995年1月晉升教授
2006年至2020年擔任生物無機與合成化學教育部重點實驗室主任
2022年擔任化學與精細化工廣東省實驗室主任
主要學術兼職：
先後兼任生物無機與合成化學教育部重點實驗室主任、中大化學院院長、中國晶體學會副理事長、中國科學院化學部常委及副主任、國家學位委員會化學學科評議組成員、國家基金委化學部專家咨詢委員會成員、國際分子篩協會金屬有機框架材料（MOF）委員會成員等職務等。
講授課程
主要講授《現代無機化學》和《單晶結構分析》等本科生、研究生課程；指導博士後、博士生、碩士生以及國内訪問學者的科研工作。
科研方向
功能配位化學與晶體工程研究，特别是配位聚合物、金屬有機框架材料等的設計與合成、結構與功能（吸附與分離、催化、光電磁、傳感）研究，以及含能分子晶體研究。
獲獎情況
2007年 國家自然科學獎二等獎（第一完成人）：配合物控制合成與晶體工程方法基礎研究
2008年 湯森路透卓越研究獎 (Thomson Reuters Research Fronts Award)
2012年 發展中國家科學院TWAS化學獎
2012年 廣東省科學技術獎一等獎(第一完成人): “微孔與磁性配位聚合物研究”
2014年 湯森路透高被引用科學家 (Thomson Reuters Highly Cited Researcher)
2015年 湯森路透高被引用科學家 (Thomson Reuters Highly Cited Researcher)
2016年 湯森路透高被引用科學家 (Thomson Reuters Highly Cited Researcher)
2017年 科睿唯安高被引用科學家 (Clarivate Highly Cited Researcher)
2017年 廣東省科學技術獎突出貢獻獎
2018年 國家級教學成果二等獎（第三獲得者）
2018年 科睿唯安高被引用科學家（Clarivate Highly Cited Researcher）
2019年 科睿唯安高被引用科學家（Clarivate Highly Cited Researcher）
2019年 第34屆花剌子模國際科學獎(34th Khwarizmi International Award）
2020年 日本配位化學學會國際獎(International Award of Japan Society of Coordination Chemistry (JSCC)
2020年 科睿唯安高被引用科學家（Clarivate Highly Cited Researcher）
2021年 科睿唯安高被引用科學家（Clarivate Highly Cited Researcher）
論著一覽
編寫教材：
《單晶結構分析原理與實踐》（與蔡繼文博士合作），科學出版社，2003年9月第一版，2007年8月第二版。
陳小明在國際刊物發表的部分論文目錄：
Selected Publications of Xiao-Ming Chen:
1. Polynuclear CuII12-MIII6 (M = Y, Nd or Gd) complexes encapsulating a ClO4– anion:
[Cu12M6(OH)24(pyb)12(H2O)18(ClO4)](ClO4)17·nH2O (pyb = pyridine betaine)
Chen, X.-M.; Aubin, S.M.J.; Wu, Y.-L.; Yang, Y.-S.; Mak, T.C.W.; Hendrickson, D.N., J. Am. Chem. Soc. 1995, 117, 9600-9601. PDF
2. Self-assembled three-dimensional coordination polymers with unusual ligand-unsupported Ag-Ag bonds: Syntheses, structures and luminescent properties
Tong, M.-L.; Chen, X.-M.; Ye, B.-H.; Ji, L.-N. Angew. Chem. Int. Ed. 1999, 38, 2237-2240. PDF
3. Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI-CuII complexes
Zhang, X.-M.; Tong, M.-L.; Chen, X.-M., Angew. Chem. Int. Ed. 2002, 41, 1029-1031. PDF
4. A novel, highly electrical conducting, single-component molecular material, [Ag2(ophen)2] (Hophen = 1H-[1,10]phenanthrolin-2-one)
Zheng, S.-L.; Zhang, J.-P.; Wong, W.-T.; Chen, X.-M., J. Am. Chem. Soc. 2003, 125, 6882-6883. PDF
5. (Review Article) Silver(I)-hexamethylenetetramine molecular architectures: From self-assembly to designed assembly
Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2003, 246, 185-202. PDF
6. Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: in-situ formation of ligands by cycloaddition of nitriles and ammonia
Zhang, J.-P.; Zheng, S.-L.; Huang, X.-C.; Chen, X.-M., Angew. Chem. Int. Ed. 2004, 43, 206-209.
7. A new route to supramolecular isomers via molecular templating: nanosized molecular polygons of copper(I) 2-methylimidazolates
Huang, X.-C.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2004, 126, 13218-13219. PDF
8. (Review Article) Metal-organic molecular architectures with 2,2’-bipyridyl-like and carboxylate ligands
Ye, B.-H.; Tong, M.-L.; Chen, X.-M., Coord. Chem. Rev. 2005, 249, 545–565. PDF
9. Copper(I) 1,2,4-triazolates and related complexes: Studies of the solvothermal ligand reactions, network topologies, and photoluminescence properties
Zhang, J.-P.; Lin, Y.-Y.; Huang, X.-C.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 5495-5506. PDF
10. Spin-canting and metamagnetism observed in a unique 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II) coordination polymer sheets
Zeng, M.-H.; Zhang, W.-X.; Sun, X.-Z.; Chen, X.-M., Angew. Chem. Int. Ed. 2005, 44, 3079-3082. PDF
11. Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer
Zhang, J.-P.; Lin, Y.-Y.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2005, 127, 14162-14163. PDF
12. Ligand-directed strategy for zeolite-type metal-organic frameworks: Zinc(II) imidazolates with unusual zeolitic topologies
Huang, X.-C.; Lin, Y.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 1557-1559. PDF
13. Assembling “magnetic nanowires” into network: A layered Co(II)-carboxylate coordination polymer exhibiting single-chain-magnet behavior
Zheng, Y.-Z.; Tong, M.-L.; Zhang, W.-X.; Chen, X.-M., Angew. Chem. Int. Ed. 2006, 45, 6310-6314. PDF
14. (Review Article) Solvothermal in-situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry
Chen, X.-M.; Tong, M.-L., Acc. Chem. Res. 2007, 40, 162-170. PDF
15. A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation
Cheng, X.-N.; Zhang, W.-X.; Lin, Y.-Y.; Zheng, Y.-Z.; Chen, X.-M., Adv. Mater. 2007, 19, 1494–1498. PDF
16. A “star” antiferromagnet: A polymeric iron(III) acetate exhibiting the coexistence of spin-frustration and long-range magnetic order
Zheng, Y.-Z.; Tong, M.-L.; Xue, W.; Zhang, W.-X.; Chen, X.-M.; Grandjean, F.; Long, G. J., Angew. Chem. Int. Ed. 2007, 46, 6076-6080. (Highlighted in Nature China) PDF
17. Single-crystal-to-single-crystal transformation from ferromagnetic discrete molecules to a spin-canting antiferromagnetic layer
Cheng, X.-N.; Zhang, W.-X.; Chen, X.-M., J. Am. Chem. Soc. 2007, 129, 15738-15739. PDF
18. Néel temperature enhanced by increasing the in-plane magnetic correlation in layered inorganic-organic hybrid materials
Zheng, Y.-Z.; Xue, W.; Zheng, S.-L.; Tong, M.-L.; Chen, X.-M., Adv. Mater. 2008, 20, 1534–1538. PDF
19. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2008, 130, 6010–6017; PDF
20. Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal
Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2009, 131, 5516–5521. (Highlighted in Nature China) Link.
21. (Review Article) Supramolecular isomerism in coordination polymers
Zhang, J.-P.; Huang, X.-C.; Chen, X.-M., Chem. Soc. Rev. 2009, 38, 2385–2396. Link
22. A highly-connected porous coordination polymer with interesting channel structure and sorption properties
Zhang, Y.-B.; Zhang, W.-X.; Feng, F.-Y.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2009, 48, 5287-5290. Link.
23. Non-classical active site for enhanced gas sorption in porous coordination polymer
Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2010, 132, 6654–6656. Link
24. Pore surface tailored SOD-type metal-organic zeolites
Zhang, J.-P.; Zhu, A.-X.; Lin, R.-B.; Qi, X.-L.; Chen, X.-M., Adv. Mater. 2011, 22, 1268–1271. PDF
25. A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide
Qi, X.-L.; Lin, R.-B.; Chen, Q.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2011, 2, 2214-2218. Link.
26. Geometry analysis and systematic synthesis of isoreticular open frameworks with a unique topology
Zhang, Y.-B.; Zhou, H.-L.; Lin, R.-B.; Zhang, C.; Lin, J.-B.; Zhang, J.-P.; Chen, X.-M., Nature Commun. 2012, 3, 642. DOI: 10.1038/ncomms1654. Link
27. (Review Article) Metal azolate frameworks: from crystal engineering to functional materials
Zhang, J.-P.; Zhang, Y.-B.; Lin, J.-B.; Chen, X.-M., Chem. Rev. 2012, 112, 1001–1033. Link
28. Strong and dynamic CO2 sorption in a flexible porous framework possessing guest chelating claws
Liao, P.-Q.; Zhou, D.-D.; Zhu, A.-X.; Jiang, L.; Lin, R.-B.; Zhang, J.-P.; Chen, X.-M., J. Am. Chem. Soc. 2012, 134, 17380-17383. Link
29. A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic compounds
He, C.-T.; Tian, J.-Y.; Liu, S.-Y.; Ouyang, G.F.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2013, 4, 351–356. Link
30. Turning on the flexibility of isoreticular porous coordination frameworks for drastically tunable framework breathing and thermal expansion
Wei, Y.-S.; Chen, K.-J.; Liao, P.-Q.; Zhu, B.-Y.; Lin, R.-B.; Zhou, H.-L.; Wang, B.-Y.; Xue, W.; Zhang, J.-P.; Chen, X.-M., Chem. Sci. 2013, 4, 1539-1546. Link
31. Direct visualization of a guest-triggered crystal deformation based on a flexible ultramicroporous framework
Zhou, H.-L.; Lin, R.-B.; He, C.-T.; Zhang, Y.-B.; Feng, N.-D.; Wang, Q.; Deng, F.; Zhang, J.-P.; Chen, X.-M., Nature Commun. 2013, 4, 2534. DOI: 10.1038 /ncomms3534. Link
32. A noble-metal-free porous coordination framework with exceptional sensing efficiency for oxygen
Lin, R.-B.; Li, F.; Liu, S.-Y.; Qi, X.-L.; Zhang, J.-P.; Chen, X.-M., Angew. Chem. Int. Ed. 2013, 52, 13429-13433. Link
33. (Invited Review) Single-crystal X-ray diffraction studies on structural transformations of porous coordination polymers
Zhang, J.-P.; Liao, P.-Q.; Zhou, H.-L.; Lin, R.-B.; Chen, X.-M., Chem. Soc. Rev. 2014, 43, 5789-5814. DOI: 10.1039/C4CS00129J. Link
34. Porous Cu(I) triazolate framework and derived hybrid membrane with exceptionally high sensing efficiency for gaseous oxygen
Liu, S.-Y.; Qi, X.-L.; Lin, R.-B.; Cheng, X.-N.; Liao, P.-Q.; Zhang, J.-P.; Chen, X.-M., Adv. Funct. Mater. 2014, 24, 5866–5872. DOI: 10.1002/adfm.201401125. Link
35. Visualizing the distinctly different crystal-to-crystal structural dynamism and sorption behaviors of interpenetration-direction isomeric coordination networks
He, Chun-Ting; Liao, Pei-Qin; Zhou, Dong-Dong; Wang, Bao-Ying; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming Chen, Chem. Sci. 2014, 5, 4755. DOI: 10.1039/C4SC01505C. Link
36. Switchable guest molecular dynamics in a perovskite-like coordination polymer toward sensitively thermal-responsive dielectric materials
Du, Zi-Yi; Xu, Ting-Ting; Huang, Bo; Su, Yu-Jun; Xue, Wei; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming; Angew. Chem. Int. Ed. 2015, 54, 914 –918. DOI: 10.1002/anie.201408491. Link
37. Monodentate hydroxide as a super strong yet reversible active site for CO2 capture from high-humidity flue gas
Liao, Pei-Qin; Zhou, Dong-Dong; Liu, Si-Yang; He, Chun-Ting; Zhang, Wei-Xiong; Jie-Peng Zhang, and Xiao-Ming Chen, Energy Environ. Sci. 2015, 8, 1011-1016. DOI: 10.1039/C4EE02717E. Link
38. Self-catalyzed aerobic oxidization of organic linker in porous crystal for on-demand regulation of sorption behaviors
Liao, P.-Q.; Zhu, A.-X.; Zhang, W.-X.; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6, 6350. doi:10.1038/ncomms7350. Link
39. Tuning fluorocarbon adsorption on isoreticular metal-organic frameworks for heat transformation applications
Lin, Rui-Biao; Li, Tai-Yang; Zhou, Hao-Long; He, Chun-Ting; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci. 2015, 6, 2516-2521. DOI: 10.1039/C4SC03985H. Link
40. Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behavior
Zhou, Hao-Long; Zhang, Yue-Biao; Zhang, J.-P.; Chen, X.-M., Nature Comm. 2015, 6, 6917. DOI: doi: 10.1038/ncomms7917. Link
41. (Invited Review) Metal cluster-based functional porous coordination polymers
Wei-Xiong Zhang, Liao, Pei-Qin; Rui-Biao Lin, Yong-Sheng Wei, Ming-Hua Zeng, Xiao-Ming Chen, Coord. Chem. Rev. 2015, 293–294, 263–278. doi: 10.1016/j.ccr.2014.12.009. Link
42. Exceptional hydrophobicity of a large-pore metal-organic zeolite
Chun-Ting He, Jiang, Lu; Ye, Zi-Ming; Krishna, Rajamani; Zhong, Zhen-Song; Liao, Pei-Qin; Xu, Jianqiao; Ouyang, Gangfeng; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2015, 137, 7217–7223. Link
43. Coordination templated [2+2+2] cyclotrimerization in porous crystal
Wei,Yong-Sheng; Zhang, Mei; Liao, Pei-Qin; Lin, Rui-Biao; Li, Tai-Yang, Shao, Guang; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8348. DOI: 10.1038/ncomms9348. Link
44. Efficient purification of ethene by ethane-trapping metal-organic framework
Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Nature Commun. 2015, 6, 8697. doi:10.1038/ncomms9697. Link
45. (Hot paper) A metal-organic framework with pore size/shape suitable for strong binding and close packing of methane
Lin, Jiao-Min; He, Chun-Ting; Liu, Yan; Liao, Pei-Qin; Zhou, Dong-Dong; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2016, 55, 4674–4678. DOI: 10.1002/anie.201511006. Link
46. An alkaline-stable, metal-hydroxide mimicking metal-organic framework for efficient electrocatalytic oxygen evolution reaction
Lu, Xue-Feng; Liao, Pei-Qin (co-first author); Wang, Jia-Wei; Wu, Jun-Xi; Chen, Xun-Wei; He, Chun-Ting; Zhang, Jie-Peng; Li, Gao-Ren; Chen, Xiao-Ming, J. Am. Chem. Soc. 2016, 138, 8336–8339. DOI: 10.1021/jacs.6b03125. Link
47. Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches
Xu, Wei-Jian; He, Chun-Ting; Chen, Shao-Li; Huang, Rui-Kang; Lin, Rui-Biao; Xue, Wei; Luo, Junhua; Zhang, Wei-Xiong; Chen, Xiao-Ming; Adv. Mater., 2016, 28, 5886–5890. DOI: 10.1002/adma.201600895. Link
48. (Hot paper) Tuning pore size in diamondoid and square lattice networks for size-selective sieving of CO2
Kai-Jie Chen, David G. Madden, Tony Pham, Katherine A. Forrest, Amrit Kumar, Qing-Yuan Yang, Wei Xue, Brian Space, John J. Perry IV, Jie-Peng Zhang, Xiao-Ming Chen and Michael J. Zaworotko, Angew. Chem. Int. Ed. 2016, 55, 10268–10272. DOI: 10.1002/anie.201603934. Link
49. Putting ultrahigh concentration of amine groups into a metal–organic framework for CO2 capture at low pressures
Liao, Pei-Qin; Chen, Xun-Wei; Liu, Si-Yang; Li, Xu-Yu; Xu, Yan-Tong; Tang, Minni; Rui, Zebao; Ji, Hongbing; Zhang, Jie-Peng; Chen, Xiao-Ming; Chem. Sci. 2016, 7, 6528-6533. DOI: 10.1039/C6SC00836D. Link
50. Flexible, luminescent metal-organic frameworks showing nonlinear/synergistic solid-solution effects on porosity and sensitivity
Liu, Si-Yang; Zhou, Dong-Dong; He, Chun-Ting; Liao, Pei-Qin; Cheng, Xiao-Ning; Xu, Yan-Tong; Ye, Jia-Wen; Zhang, Jie-Peng; Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2016, 55, 6021–16025. DOI: 10.1002/anie.201608439. Link
51. Modular and stepwise synthesis of a hybrid metal-organic framework for efficient electrocatalytic oxygen evolution
Shen, Jian-Qiang; Liao, Pei-Qin; Zhou, Dong-Dong; He, Chun-Ting; Wu, Jun-Xi; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 1778–1781. DOI: 10.1021/jacs.6b12353. Link
52. A cage-confinement pyrolysis route to ultrasmall tungsten carbide nanoparticles for efficient hydrogen evolution
Xu, Yan-Tong; Xiao, Xiaofen; Ye, Zi-Ming; Zhao, Shenlong; Shen, Rongan; He, Chun-Ting; Zhang, Jie-Peng; Li, Yadong; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 139, 5285–5288. DOI: 10.1021/jacs.7b00165. Link
53. A molecular perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics
Xu, Wei-Jian; Li, Peng-Fei; Tang, Yuan-Yuan; Zhang, Wei-Xiong; Xiong, Ren-Gen; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 6369–6375. DOI: 10.1021/jacs.7b01334. Link
54. Controlling guest conformation for efficient purification of 1,3-butadiene
Liao, Pei-Qin; Huang, Ning-Yu; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming, Science, 2017, 356, 1193-1196. DOI: 10.1126/science.aam7232. Link
55. A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds
Wang, Li; He, Chun-Ting; Zeng, Ying; Ji, Cheng-Min; Luo, Jun-Hua; Du, Zi-Yi; Zhang, Wei-Xiong; Chen, Xiao-Ming, J. Am. Chem. Soc. 2017, 139, 8086–8089. DOI: 10.1021/jacs.7b02981. Link
56. Hyperfine adjustment of flexible pore-surface pockets enables smart recognitions of gas size and quadrupole moment
He, Chun-Ting; Ye, Zi-Ming; Xu, Yan-Tong; Zhou, Dong-Dong; Zhou, Hao-Long; Chen, Da; Zhang, Jie-Peng; Chen, Xiao-Ming, Chem. Sci. 2017, 8, 7560–7565. DOI: 10.1039/c7sc03067c. Link
57. Hydroxide ligands cooperate with catalytic centers in metal-organic frameworks for efficient photocatalytic CO2 reduction
Wang, Yu; Huang, Ning-Yu; Shen, Jian-Qiang; Liao, Pei-Qin; Chen, Xiao-Ming; Zhang, Jie-Peng; J. Am. Chem. Soc. 2018, 140, 38–41. Link
58. Mesoporous metal-organic frameworks with exceptionally high working capacities for adsorption heat transformation
Mo, Zong-Wen; Zhou, Hao-Long; Dong-Dong; Zhou, Rui-Biao Lin, Liao, Pei-Qin; He, Chun-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming, Zhang, Jie-Peng; Adv. Mater. 2018, 30, 1704350. adma.201704350. Link
59. Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal
Liu, Jing-Yan; Zhang, Shi-Yong; Zeng, Ying; Shu, Xia; Du, Zi-Yi; He, Chun-Ting; Zhang; Wei-Xiong, Chen, Xiao-Ming, Angew. Chem. Int. Ed. 2018, 10.1002/anie.201802580. Link
