張偉雄

教授

電子郵件

zhangwx6@mail.sysu.edu.cn

基本情況

姓名：張偉雄

性别：男

出生年月：1981-11

籍貫：廣東梅州

職位：教授，博士生導師

聯系方式

郵箱：zhangwx6@mail.sysu.edu.cn

通訊地址：廣州市番禺區小谷圍街道太阳集团app首页東校區化學材料綜合樓

郵編：510006

教育經曆

2004.09—2009.06：太阳集团app首页，無機化學專業碩博連讀，博士

2000.09—2004.06：太阳集团app首页，應用化學專業，學士

工作經曆

2018.04至今：太阳集团1088vip，教授
2012.08—2018.04：太阳集团1088vip，副教授
2010.06—2012.08：日本東北大學，日本學術振興會（JSPS）博士後
2009.07—2010.06：太阳集团1088vip，科研助理

講授課程

無機化學
功能配位化學
高等無機化學
單晶結構分析

科研方向

功能配合物的晶體工程，重點開展多組分緻密晶體組裝及其相态變化研究。已發表論文140篇，引用超1萬次，H指數51。 Researcher ID: D-3365-2011 (https://www.webofscience.com/wos/author/record/D-3365-2011)

科研項目

國家自然科學基金面上項目，22071273，2021-2024
國家自然科學基金優青項目，21722107，2018-2020
國家自然科學基金面上項目，21671202，2017-2020
國家自然科學基金青年項目，21301198，2014-2016

獲獎情況

2020日本化學會傑出報告獎（Distinguished Lectureship Awards）
2017 國家優秀青年科學基金
2016 廣東省特支計劃科技創新青年拔尖人才
2016 廣州市珠江科技新星

論著一覽

邀請綜述與專著章節：

5) Zhang Wei-Xiong*; Chen Shao-Li; Shang Yu; Chen Xiao-Ming*
Molecular perovskites as a new platform for designing advanced multi-component energetic crystals
Energ. Mater. Front. 2020, 1, 123.

4) Zhang W.-X.; Zeng M.-H.; Chen X.-M.
Porous Molecular Magnets, Molecular Magnetic Materials: Concepts and Applications
Editor: Barbara Sieklucka, Dawid Pinkowicz, Wiley-VCH Verlag GmbH & Co. KGaA, 2017: 253-278 (Book Chapter)

3) Xu W.-J.; Du Z.-Y.; Zhang W.-X.*; Chen X.-M.
Structural phase transitions in perovskite compounds based on diatomic or multiatomic bridges
CrystEngComm 2016, 18, 7915-7928.

2) Zhang W.-X.*; Liao P.-Q.; Lin R.-B.; Wei Y.-S.; Zeng M.-H.*; Chen X.-M.*
Metal cluster-based functional porous coordination polymers
Coord. Chem. Rev. 2015, 293-294, 263-278.

1) Zhang W.-X.*; Ishikawa R.; Breedlove B. K.; Yamashita H.*
Single-chain magnets: beyond the Glauber model
RSC Adv. 2013, 3, 3772−3798.

部分論文目錄（* 表示通訊聯系人）

2023年

46) Liu D.-X.; Zhu H.-L.; Zhang, W.-X.*; Chen, X.-M.
Nonlinear optical glass-ceramic from a new polar phase-transition organic-inorganic hybrid crystal
Angew. Chem. Int. Ed. 2023, 62, e202218902.

45) Yu Z.-H.; Liu D.-X.; Ling Y.-Y.; Chen X.-X.; Shang Y.; Chen S.-L.; Ye Z.-M.; Zhang, W.-X.*; Chen X.-M.
Periodate-based molecular perovskites as promising energetic biocidal agents
Sci. China Mater. 2023, DOI: 10.1007/s40843-022-2257-6.

44) Liu D.-X.; Yu Z.-H.; Chen X.-X.; Zhang, W.-X.*; Chen, X.-M.
Crystal structures and phase transitions in two new hybrid crystals: (Me₃NCH₂CH₂X)₄[Ni(NCS)₆] (X = Cl and Br)
Chin. Chem. Lett. 2023, 34, 107310.

2022年

43) Zeng Y.; Hu C.-L.; Xu W.-J.; Zeng T.-W.; Zhu Z.-X.; Chen X.-X.; Liu D.-X.; Chen Y.-J.; Zhang Y.-B.; Zhang, W.-X.*; Chen X.-M.
An exceptional thermally-induced four-state nonlinear-optical switch arising from stepwise molecular dynamic changes in a new hybrid salt
Angew. Chem. Int. Ed. 2022, 61, e202110082.

42) Ye H.; Chen X.-X.; Liu D.-X.; Zhao B.-Q.; Li Y.-B.; Zeng Y.; Zhang, W.-X.*; Chen X.-M.
Subtly tuning intermolecular hydrogen bonds in hybrid crystals to achieve ultrahigh-temperature molecular ferroelastic
Chem. Sci. 2022, 13, 14124.

41) Gong Y.-P.; Chen X.-X.; Huang G.-Z.; Zhang, W.-X.*; Chen X.-M.
Ferroelasticity, thermochromism, semi-conductivity, and ferromagnetism in a new layered perovskite: (4-fluorophenethylaminium)₂[CuCl₄]
J. Mater. Chem. C 2022, 10, 5482.

40) Liu D.-X.; Chen X.-X.; Ye Z.-M.; Zhang, W.-X.*; Chen, X.-M.
High- and low-temperature dual ferroelasticity in a new hybrid crystal: (Me₃NCH₂CH₂OH)₄[Ni(NCS)₆]
Sci. China Mater. 2022, 65, 263.

39) Chen X.-X.; Liu D.-X.; Gong Y.-P.; Wang S.-S.; Zhang, W.-X.*; Chen X.-M.
Above-room-temperature ferroelastic phase transitions in two tetrafluoroborate-based hexagonal molecular perovskites
Inorg. Chem. 2022, 61, 2219.

38) Sun C.-C^#.; Li W.^#; Liu D.-X.; Du Z.-Y.*; He C.-T.; Zhang, W.-X.*; Chen X.-M.
Insights into the molecular dynamics of quasi-spherical (chloromethyl)triethylammonium confined in a weakly bound ionic cocrystal
Inorg. Chem. 2022, 61, 7201.

37) Shang Y.; Chen S.-L.*; Yu Z.-H.; Huang R.-K.; He C.-T.; Ye Z.-M.; Zhang, W.-X.*; Chen X.-M.
Silver(I)-based molecular perovskite energetic compounds with exceptional thermal stability and energetic performance
Inorg. Chem. 2022, 61, 4143.

36) Li Q.-Y.; Li M.-F.; Chen X.-X.; Gong Y.-P.; Liu D.-X.; Xu W.-J.; Zhang, W.-X.*
Near-room-temperature dielectric switch and thermal expansion anomaly in a new hybrid crystal: (Me₂NH₂)[CsFe(CN)₅(NO)]
CrystEngComm 2022, 24, 4864.

35) Huang B.; Wang P.; Zhang, W.-X.*; Chen X.-M.
Magnetic-dielectric bistabilities and magnetodielectric coupling effects in a new layered hybrid perovskite: (C₆H₅(CH₂)₄NH₃)₂[MnCl₄]
Mater. Adv. 2022, 3, 9103.

34) Chen S.-L.*; Shang Y.; Jiang J.; Huang M.; Ren J.-T.; Guo T.; Yu C.-X.; Zhang, W.-X.*; Chen X.-M.
A new nitrate-based energetic molecular perovskite as a modern edition of black powder
Energ. Mater. Front. 2022, 3, 122.

33) Shang Y.; Sun L.-Y.; Ye Z.-M.; Chen S.-L.*; Zhang, W.-X.*; Chen X.-M.
Phase transition and thermal expansion of molecular perovskite energetic crystal (C₆N₂H₁₄)(NH₄)(ClO₄)₃ (DAP-4)
FirePhysChem 2022, 2, 221.

32) Li W.; Liu D.-X.; Hu W.-Y.; Liu Q.-Y.; Du Z.-Y.*; He C.-T.; Zhang, W.-X.*; Chen X.-M.
A crystalline supramolecular rotor functioned by dual ultrasmall polar rotators
Chin. J. Chem. 2022, 40, 1917.

2021年

31) Chen X.-X.; Zhang X.-Y.; Liu D.-X.; Huang R.-K.; Wang S.-S.; Xiong L.-Q.; Zhang, W.-X.*; Chen X.-M.
Room-temperature ferroelectric and ferroelastic orders coexisting in a new tetrafluoroborate-based perovskite
Chem. Sci. 2021, 12, 8713.

30) Meng Q.-R.; Xu, W.-J.; Hu W.-H.; Ye H.; Chen X.-X.; Yuan, W.; Zhang, W.-X.*; Chen X.-M.
An unprecedented hexagonal double perovskite organic–inorganic hybrid ferroelastic material: (piperidinium)₂[KBiCl₆]
Chem. Commun. 2021, 57, 6292.

29) Jia Z.-H.; Liu J.-Y.; Liu D.-X.; Zhang S.-Y.; Du Z.-Y.*; He C.-T.*; Zhang, W.-X.*; Chen X.-M.
Four-step thermosensitive dielectric response arising from motionable low-symmetry ammonium confined in deformable supramolecular cages
J. Mater. Chem. C 2021, 9, 8076.

28) Xu W.-J.; Romanyuk K.; Martinho J.; Zeng Y.; Ushakov A.; Shur V.; Tselev A.; Zhang, W.-X.*; Chen X.-M., Kholkin A.*; Rocha J.*
Statics and dynamics of ferroelectric domains in molecular multiaxial ferroelectric (Me₃NOH)₂[KCo(CN)₆]
J. Mater. Chem. C 2021, 9, 10741.

27) Ye H.^#; Hu W.-H.^#; Xu W.-J.; Zeng Y.; Chen X.-X.; Huang R.-K.; Zhang, W.-X.*; Chen X.-M.
Two enantiomeric perovskite ferroelectrics with a high T_c raised by inserting intermolecular hydrogen bonds
APL Mater. 2021, 9, 031102.

26) Liu D.-X.; Xie K.-P.; Zhang, W.-X.*; Zeng M.-H.; Chen, X.-M.
Structural insights into a new family of three-dimensional thiocyanate-bridged molecular double perovskites
CrystEngComm 2021, 23, 2208.

2020年

25) Xu W.-J.; Romanyuk K.; Martinho J.; Zeng Y.; Zhang X.-W.; Ushakov A.; Shur V.; Zhang W.-X.*; Chen X.-M.; Kholkin A.*; Rocha J.*
A photo-responsive organic-inorganic hybrid ferroelectric designed at molecular level
J. Am. Chem. Soc. 2020, 146, 16990.

24) Zhang S.-Y.^#; Shu X.^#; Zeng Y.^#; Liu Q.-Y.; Du Z.-Y.*; He C.-T.*; Zhang W.-X.*; Chen X.-M.
Molecule-based nonlinear optical switch with highly tunable on-off temperature using a dual solid solution approach
Nat. Commun. 2020, 11, 2752.

23) Shang Y.; Yu Z.-H.; Huang R.-K.; Chen S.-L.*; Liu D.-X.; Chen X.-X.; Zhang W.-X.*; Chen X.-M.
Metal-free hexagonal perovskite high-energetic materials with NH₃OH⁺/NH₂NH₃⁺ as B-site cations
Engineering 2020, 6, 1013.

22) Xu W.-J.; Zeng Y.; Yuan W.; Zhang W.-X.*; Chen X.-M.
Room-temperature large entropy change in a new hybrid ferroelastic with unconventional bond-switching mechanism
Chem. Commun. 2020, 56, 10054.

21) Huang R.-K.; Chen X.-X.; Xiao Z.-F.; Liu D.-X.; Zhang W.-X.*; Chen X.-M.
Enhancing switchable dielectric property for crystalline supramolecular rotor compounds by adding polar components
Chem. Commun. 2020, 56, 4114.

20) Qiu R.-G.; Chen X.-X.; Huang R.-K.; Zhou D.-D.; Xu W.-J.*; Zhang W.-X.*; Chen X.-M.
Nitroprusside as a promising building block to assemble organic-inorganic hybrid for thermo-responsive switching material
Chem. Commun. 2020, 56, 5488.

19) Shang Y.; Huang R.-K.; Chen S.-L.*; He C.-T.; Yu Z.-H.; Ye Z.-M.; Zhang W.-X.*; Chen X.-M.
Metal-free molecular perovskite high-energetic materials
Cryst. Growth Des. 2020, 20, 1891.

2019年

18) Huang R.-K.; Wang S.-S.; Liu D.-X.; Li, X.; Song J.-M.; Xia Y.-H.; Zhou D.-D.*; Huang J.; Zhang W.-X.*; Chen X.-M.
Supercooling behavior and dipole-glass-like relaxation in a three-dimensional water framework
J. Am. Chem. Soc. 2019, 141, 5645.

17) Wang S.-S.; Chen X.-X.; Huang B.; Huang R.-K.; Zhang W.-X.*; Chen X.-M.
Unique freezing dynamics of flexible guest cations in the first molecular postperovskite ferroelectric: (C₅H₁₃NBr)[Mn(N(CN)₂)₃]
CCS Chem. 2019, 1, 448.

16) Huang R.-K.; Xiao Z.-F.; Liu D.-X.; Zhang W.-X.*; Chen X.-M.
Unprecedented water-controlled rotator–stator conversion of supramolecular rotors in crystals
Chem. Commun. 2019, 55, 7159.

15) Hu W.-H.; Xu W.-J.; Meng Q.-R.; Zhang X.-W.; He C.-T.; Zhang W.-X.*; Chen X.-M.
Switching hydrogen bonds to readily interconvert two room-temperature long-term stable crystalline polymorphs in chiral molecular perovskite
Chem. Commun. 2019, 55, 11555.

14) Yuan W.; Zeng Y.; Tan Y.-Y.; Zhou J.-H.; Xu W.-J.*; Zhang W.-X.*; Chen X.-M.
A new ferroelastic hybrid material with a large spontaneous strain: (Me₃NOH)₂[ZnCl₄]
Chem. Commun. 2019, 55, 8983.

13) Li W., Zeng Y.; Shu X. He C.-T.; Du Z.-Y.*; Zhang W.-X.*; Chen X.-M.
Isostructural phase transition and tunable water rotation within a unique solid rotor system
J. Mater. Chem. C 2019, 7, 13176.

12) Wang S.-S.; Huang R.-K.; Chen X.-X.; Xu W.-J.; Zhang W.-X.*; Chen X.-M.*
Temperature-induced structural phase transitions in two new postperovskite coordination polymers
Cryst. Growth Des. 2019, 19, 1111.

2018年

11) Chen S.-L.; Yang Z.-R.; Wang B.-J.; Shang Y.; Sun L.-Y.; He C.-T.; Zhou H.-L.; Zhang W.-X.*; Chen X.-M.*
Molecular perovskite high-energetic materials
Sci. China Mater. 2018, 1123. (News Link: What else can molecular perovskite do?)

10) Liu J.-Y.; Zhang S.-Y.; Zeng Y.; Shu X.; Du Z.-Y.*; He C.-T.*; Zhang W.-X.*; Chen, X.-M.
Molecular dynamics, phase transition and frequency-tuned dielectric switch of an ionic co-crystal
Angew. Chem. Int. Ed. 2018, 57, 8032.

9) Huang B.; Zhang J.-Y.; Huang R.-K.; Chen M.-K.; Xue W.; Zhang W.-X.*; Zeng M.-H.; Chen, X.-M.
Spin-reorientation-induced magnetodielectric coupling effects in two layered perovskite magnets
Chem. Sci. 2018, 9, 7413.

8) Chen S.-L.^#; Shang Y.^#; He C.-T.; Sun L.-Y.; Ye Z.-M.; Zhang W.-X.*; Chen X.-M.*
Optimizing the oxygen balance by changing the A-site cations in molecular perovskite high-energetic materials
CrystEngComm 2018, 20, 7458.

7) Xu W.-J.; Zeng Y.; Yuan W.; Qiu R.-G.; Zhang W.-X.*; Chen X.-M.
Room-temperature optic-electric duple bistabilities induced by plastic transition
Chem. Commun. 2018, 54, 3347.

6) Wang S.-S.; Chen X.-X.; Huang B.; Su Y.-J.; Zhang W.-X.*; Zeng M.-H.; Chen X.-M.
Bromocholine bromide is a molecular ferroelectric with moderate phase transition temperature
J. Mater. Chem. C 2018, 6, 2221.

2017年以前

5) Xu W.-J.; Li P.-F.; Tang Y.-Y.; Zhang W.-X.*; Xiong R.-G.; Chen X.-M.
A molecular perovskite with switchable coordination bonds for high-temperature multi-axial ferroelectrics
J. Am. Chem. Soc. 2017, 139, 6369-6375. (Highlighted in Science)

4) Li W.; He C.-T.; Zeng Y.; Ji C.-M.; Du Z.-Y.*; Zhang W.-X.*; Chen X.-M.
A crystalline supramolecular gyroscope with a water molecule as an ultra-small polar rotator modulated by charge-assisted hydrogen bonds
J. Am. Chem. Soc. 2017, 139, 8086-8089.

3) Shi Q.; Xu W.-J.; Huang R.-K.; Zhang W.-X.*; Li Y.; Wang P.-F.; Shi F.-N.*; Li L.-B.; Li J.-P.; Dong J.-X.*
Zeolite CAN and AFI-type ZIFs with large 12-MR pore openings synthesized using bulky amides as structure-directing agents
J. Am. Chem. Soc. 2016, 138, 16232-16235.

2) Xu, W.-J.; He, C.-T.; Ji, C.-M.; Chen, S.-L.; Huang, Y.-K.; Lin, R.-B.; Luo, J.-H.; Zhang, W.-X.*; Chen, X.-M.
Molecular dynamics of flexible polar cation in variable confined space: toward exceptional two-step nonlinear optical switches
Adv. Mater. 2016, 28, 5886.

1) Du Z.-Y.; Xu T.-T.; Huang B.;Su Y.-J.; Xue W.; He C.-T.; Zhang W.-X.*; Chen, X.-M.
Switchable guest molecular dynamics in a Perovskite-like coordination polymer toward sensitive thermo-responsive dielectric materials
Angew. Chem. Int. Ed. 2015, 54, 914.

張偉雄