基本情況

姓名：王高翔

性别：男

出生年月：1994-02

籍貫：湖北荊州

職位：副教授，博士生導師

 

聯系方式

郵箱：wanggx29@mail.sysu.edu.cn

通訊地址：廣州市大學城外環東路132号太阳集团1088vip

郵編：510006

 

教育經曆

2016.09-2021.07：北京大學，有機化學，博士

2012.09-2016.07：北京大學，化學，學士

 

工作經曆

2025.01-至今：太阳集团app首页，太阳集团1088vip，副教授

2024.05-2025.01：中國科學院大連化學物理研究所，催化基礎國家重點實驗室，副研究員

2021.07-2024.05：北京大學，太阳集团1088vip，博士後

 

科研方向

高活性金屬有機配合物的合成，結構與反應化學

N2、NO、O2等小分子活化與轉化的反應機制

金屬有機配合物的電子結構光譜學表征與理論計算

 

科研項目

國家自然科學基金重大研究計劃，第二配位域協同的新型仿生分子團簇的精準構築與催化固氮功能，2025-01-01至2027-12-31，參與

 

獲獎情況

中國科學院大連化學物理研究所優秀博士人才（2024）

北京大學優秀博士後（2023）

北京大學博士研究生校長獎學金（2019）

 

主要論著

  1. Yin, Z.-B.; Wang, G.-X.; Yan, X.; Wei, J.; Xi, Z. Construction of N-E bonds via Lewis acid-promoted functionalization of chromium-dinitrogen complexes. Nat. Commun. 2025, 16, DOI: 10.1038/s41467-025-55998-5.
  2. Chen, X.; Wang, G.-X.; Lv, Z.-J.; Wei, J.; Xi, Z. Monomethylation and -protonation of Lutetium Dinitrogen Complex. J. Am. Chem. Soc. 2024, 146, 17624–17628.
  3. Wang, G.-X.; Shan, C.; Chen, W.; Wu, B.; Zhang, P.; Wei, J.; Xi, Z.; Ye, S. Unusual Electronic Structures of an Electron Transfer Series of [Cr(μ-η1:η1-N2)Cr]0/1+/2. Angew. Chem. Int. Ed. 2024, 63, e202315386.
  4. Wang, G.-X.; Yin, Z.-B.; Wei, J.; Xi, Z. Dinitrogen Activation and Functionalization Affording Chromium Diazenido and Hydrazido Complexes. Acc. Chem. Res. 2023, 56, 3211–3222.
  5. Wang, X.; Wang, Y.; Wu, Y.; Wang, G.-X.; Wei, J.; Xi, Z. Syntheses and Characterizations of Hetero-Bimetallic Chromium-Dinitrogen Transition-Metal Complexes. Inorg. Chem. 2023, 62, 18641–18648.
  6. Wang, G.-X.; Wang, X.; Jiang, Y.; Chen, W.; Shan, C.; Zhang, P.; Wei, J.; Ye, S.; Xi, Z. Snapshots of Early-Stage Quantitative N2 Electrophilic Functionalization. J. Am. Chem. Soc. 2023, 145, 9746–9754.
  7. Yin, Z.-B.; Wu, B.; Wang, G.-X.; Wei, J.; Xi, Z. Dinitrogen Functionalization Affording Chromium Diazenido and Side-on η2-Hydrazido Complexes. J. Am. Chem. Soc. 2023, 145, 7065–7070.
  8. Wu, B.; Feng, R.; Yin, Z.-B.; Yan, H.; Wang, X.; Wang, G.-X.; Wei, J.; Xi, Z. Synthesis and structural analysis of titanium-μ-dinitrogen complex supported by di-anionic guanidinate ligands. Sci. China Chem. 2023, 66, 755–759.
  9. Wang, G.-X.; Yan, X.; Yin, J.; Yin, Z.-B.; Wei, J.; Xi, Z. Cobalt Cyclopentadienyl-Phosphine Dinitrogen Complexes. Chem. Eur. J. 2022, 28, e202202803.
  10. Wang, G.-X.; Chen, W.; Yan, X.; Xie, F.; Wei, J.; Ye, S.; Xi, Z. Preparation and Characterization of a 19-Electron Ni(I) Complex Bearing a Cyclopentadienyl-Phosphine Ligand. Organometallics 2022, 41, 2227–2231.
  11. Shi, X.; Wang, Q.; Qin, C.; Wu, L.-J.; Chen, Y.; Wang, G.-X.; Cai, Y.; Gao, W.; He, T.; Wei, J.; Guo, J.; Chen, P.; Xi, Z. Synthesis of Pyrimidines from Dinitrogen and Carbon. Natl. Sci. Rev. 2022, 9, nwac168.
  12. Li, H.-J.; Feng, R.; Wang, G.-X.; Wei, J.; Xi, Z. Dinitrogen activation by a phosphido-bridged binuclear cobalt complex. Dalton Trans. 2022, 51, 16811–16815.
  13. Zhong, M.; Cui, X.; Wu, B.; Wang, G.-X.; Zhang, W.-X.; Wei, J.; Zhao, L.; Xi, Z. Dinitrogen Functionalization Affording Structurally Well-Defined Cobalt Diazenido Complex. CCS Chem. 2021, 3, 856–863.
  14. Wang, G.-X.; Yin, J.; Li, J.; Yin, Z.-B.; Wu, B.; Wei, J.; Zhang, W.-X.; Xi, Z. Dinitrogen Activation of Cyclopentadienyl-Phosphine-Iron Complexes of Three Different Valences. CCS Chem. 2021, 3, 308–316.
  15. Li, J.; Yin, J.; Wang, G.-X.; Yin, Z.-B.; Zhang, W.-X.; Xi, Z. Synthesis and reactivity of asymmetric Cr(I) dinitrogen complexes supported by cyclopentadienyl-phosphine ligands. Chem. Commun. 2019, 55, 9641–9644.
  16. Yin, J.; Li, J.; Wang, G.-X.; Yin, Z.-B.; Zhang, W.-X.; Xi, Z. Dinitrogen Functionalization Affording Chromium Hydrazido Complex. J. Am. Chem. Soc. 2019, 141, 4241–4247.
  17. Wang, G.-X.; Yin, J.; Li, J.; Yin, Z.-B.; Zhang, W.-X.; Xi, Z. Synthesis and Characterization of Manganese(II) Complexes Supported by Cyclopentadienyl-Phosphine Ligands. Inorg. Chem. Front. 2019, 6, 428–433.
  18. Ke, X.-S.; Ning, Y.; Tang, J.; Hu, J.-Y.; Yin, H.-Y.; Wang, G.-X.; Yang, Z.-S.; Jie, J.; Liu, K.; Meng, Z.-S.; Zhang, Z.; Su, H.; Shu, C.; Zhang, J.-L. Gadolinium(III) Porpholactones as Efficient and Robust Singlet Oxygen Photosensitizers. Chem. Eur. J. 2016, 22, 9676–9686.
  19. Hu, J.-Y.; Zhang, J.; Wang, G.-X.; Sun, H.-L.; Zhang, J.-L. Constructing a Catalytic Cycle for C-F to C-X (X = O, S, N) Bond Transformation Based on Gold-Mediated Ligand Nucleophilic Attack. Inorg. Chem. 2016, 55, 2274–2283.