基本情況
姓名：許偉劍
性别：男
出生年月：1990-08
籍貫：海南儋州
職位：副教授，博士生導師
聯系方式
郵箱：xuweijian@mail.sysu.edu.cn
通訊地址：廣州市大學城外環東路132号太阳集团1088vip
郵編：510006
教育經曆
2012.09-2017.06: 太阳集团app首页，無機化學，博士
2008.09-2012.06: 江蘇大學，應用化學，學士
工作經曆
2025.01 - 至今：太阳集团app首页，太阳集团1088vip，副教授
2022.04-2024.12：葡萄牙阿威羅大學，初級研究員
2018.07-2021.12：葡萄牙阿威羅大學，博士後
2017.07-2018.06：太阳集团app首页，太阳集团1088vip，特聘副研究員
科研方向
有機無機雜化晶态材料化學及分子鐵電化學
科研項目
國家自然科學基金青年科學基金項目，（項目負責人，2019.01–2021.12）
獲獎情況
博士研究生國家獎學金（2016年）
主要論著
(*表示通訊聯系人)
1)Hydrogen-Bonding-Driven Design of Organic–Inorganic Hybrid Ferroelastics with Reversible Photoisomerization
Verissimo, L.; Fang, Z.-L.; Xu, W.-J.*; Martinho, M. G.;Yuan, W.; Zhang,W-X.*; Chen, X.-M.; Kholkin, A.*; Rocha, J.*
Inorg. Chem., 2025, 64, 2154−2163.
2)Switchable K–O bonds unveiling anomalous ferroelastic transitions in a polar hybrid crystal
Li, Y.-B.; Xu, W.-J.*; Chen, X.-X.; Liu, D.-X.; Wang, Z-S.; Zhang,W-X.*
Sci. China Mater., 2024, 67, 3408−3414.
3)Equatorial–Axial Conformational Dynamics Enabling Thermoresponsive SHG Switch in a Homochiral Hybrid Compound
Guo, M.-Y.; Li, M.-F.; Chen, X.-X.; Xu, W.-J.*; Zhang,W-X.*
ACS Appl. Opt. Mater., 2024, 2, 2612−2620.
4)Designing dynamic coordination bonds in polar hybrid crystals for a high-temperature ferroelastic transition
Li, Y.-B.; Chen, X.-X.; Xu, W.-J.; Gong, Y.-P.; Ye, H.; Wang, Z.-S.; Zhang,W.-X.*
Chem. Sci., 2024, 15, 3661−3669.
5)Multi-stimuli responsive behaviors in a new chiral hybrid nitroprusside salt (R-3-hydroxypyrrolidinium)2[Fe(CN)5(NO)]
Li, M.-F.; Guo, M.-Y.; Liu, D.-X.; Chen, X.-X.; Xu, W.-J.*; Zhang,W-X.*
Chin. Chem. Lett., 2024, 35, 109507.
6)Molecular Design of a Metal-Nitrosyl Ferroelectric with Reversible Photoisomerization
Xu, W.-J.*; Li, M.-F.; Garcia, A. R.; Romanyuk, K.; Martinho, M. G.;Zelenovskii, P.; Tselev, A.; Verissimo, L.; Zhang,W-X.*; Chen, X.-M.; Kholkin, A.*; Rocha, J.*
J. Am. Chem. Soc., 2023, 145, 13663−13673.
7)A hybrid double perovskite ferroelastic exhibiting the highest number of orientation states
Xu, W.-J.*; Zelenovskii, P.; Tselev, A.; Verissimo, L.; Romanyuk, K.; Yuan, W.; Zhang,W-X.*;Kholkin, A.*; Rocha, J.*
Chem. Commun., 2023, 59, 11264−11267.
8)An Exceptional Thermally Induced Four-State Nonlinear Optical Switch Arising from Stepwise Molecular Dynamic Changes in a New Hybrid Salt
Zeng, Y, Hu, C-L, Xu, W.-J.; Zeng, W.-T., Zhu, Z.-X., Chen, X.-X., Liu, D.-X., Chen, Y.-J., Zhang, Y.-B., Zhang, W,-X.,* and Chen, X.-M.
Angew. Chem. Int. Ed. 2022, 61, e202110082.
9)Statics and dynamics of ferroelectric domains in molecular multiaxial ferroelectric (Me3NOH)2[KCo(CN)6]
Xu, W.-J.*; Romanyuk, K,; Zeng, Y.; Ushakov, A.; Vladimir S.; Tselev A.; Zhang,W-X.*; Chen, X.-M.; Kholkin, A.*; Rocha, J.*
J. Mater. Chem. C, 2021, 9, 10741−10748 (Hot paper).
10)An unprecedented hexagonal double perovskite organic-inorganic hybrid ferroelastic: (piperidinium)2[KBiCl6]
Meng, Q,-R.; Xu, W.-J.; Hu, W.-H.; Ye, H.; Chen, X.-X.; Yuan, W.; Zhang, W.-X.*; Chen, X.-M.
Chem. Commun., 2021, 57, 6292−6295.
11)Two enantiomeric perovskite ferroelectrics with a high Tc raised by inserting intermolecular hydrogen bonds
Ye, H.; Hu, W.-H.; Xu, W.-J.; Zeng, Y.; Chen, X.-X.; Huang, R.-K.; Zhang, W.-X.*; Chen, X.-M.
APL Mater.; 2021, 9, 031102.
12)Photoresponsive organic-inorganic hybrid ferroelectric designed at the molecular level
Xu, W.-J.; Romanyuk, K,; Martinho, M. G.; Zeng, Y.; Zhang, X.-W.; Ushakov, A.; Vladimir S.; Zhang,W-X.*; Chen, X.-M.; Kholkin, A.*; Rocha, J.*
J. Am. Chem. Soc.,2020, 142, 16990−16998.
13)A large room-temperature entropy change in a new hybrid ferroelastic with an unconventional bond-switching mechanism
Xu, W.-J.; Zeng,Y.; Yuan, W.; Zhang, W.-X.*; Chen, X.-M.
Chem. Commun., 2020, 56, 10054−10057.
14)Nitroprusside as a promising building block to assemble an organic−inorganic hybrid for thermo-responsive switching materials
Qiu, R.-G.; Chen, X.-X.; Huang, R.-K.; Zhou, D.-D.; Xu,W.-J.*; Zhang, W.-X.*; Chen, X.-M.
Chem. Commun., 2020, 56, 5488−5491 (Hot paper).
15)Hybrid organic-inorganic perovskites: polar properties and applications
Xu, W.-J.; Kopylb. S.; Kholkin, A*; Rocha, J.
Coord. Chem. Rev.2019, 387, 398−414.
16)A new ferroelastic hybrid material with a large spontaneous strain: (Me3NOH)2[ZnCl4]
Yuan, W.; Zeng,Y.; Tan, Y.-Y.; Zhou, J.-H.; Xu, W.-J.*; Zhang, W.-X.;* Chen, X.-M.
Chem. Commun., 2019, 55, 8983−8986.
17)Switching hydrogen bonds to readily interconvert two room-temperature long-term stable crystalline polymorphs in chiral molecular perovskites
Hu, W.-H.; Xu, W.-J.; Meng, Q.-R.; Zhang, X.-W.; He, C.-T.; Zhang, W.-X.*; Chen. X.-M.;
Chem. Commun., 2019, 55, 11555−11558.
18)Temperature-induced structural phase transitions in two new postperovskite coordination polymers
Wang, S.-S.; Huang, R.-K.; Chen, X.-X.; Xu, W.-J.; Zhang, W.-X.*; Chen, X.-M.*
Cryst. Growth Des.,2019, 19, 1111−1117.
19)Room-temperature optic-electric duple bistabilities induced by plastic transition.
Xu, W.-J.; Zeng, Y.; Yuan, W.; Qiu, R.-G.; Zhang, W.-X.*; Chen, X.-M.
Chem. Commum., 2018, 54, 3347−3350.
20)Direct synthesis of an aliphatic amine functionalized metal–organic framework for efficient CO2 removal and CH4 purification
Huang, N.-Y.; Mo, Z.-W.; Li, L.-J.; Xu, W.-J.; Zhou, H.-L.; Zhou, D.-D.; Liao, P.-Q.; Zhang, J.-P.*; Chen X.-M.
CrystEngComm., 2018, 20, 5969−5975.
21)A molecular perovskite with switchable coordination bonds for high-temperature Multiaxial ferroelectrics
Xu, W.-J.; Li, P.-F.; Tang, Y.-Y.; Zhang, W.-X.*; Xiong, R.-G.; Chen, X.-M.
J. Am. Chem. Soc., 2017, 139, 6369−6375. (ESI highly cited paper; highlighted in Science)
22)Structural phase transitions, dielectric bistability and luminescence of two bulky ion-pair crystals [N(C3H7)4]2[Ln(NO3)5] (Ln = Tb, Dy).
Zhang, S.-Y.; Liao, J.-S.; Xu, W.-J.; Liang, F.-Y.; Peng, G.-H.; Liu, S.-J.; Wen, H.-R.*; Du, Z.-Y.*
New J. Chem., 2017, 41, 9963−9968.
23)Deformable Mn(III)–Schiff-base dimer for anomalously large positive and negative anisotropic thermal expansions.
Su, Y.-J.; Wei, K.-X.; Huang, B.; Xu, W.-J.; Zhang, W.-X.*; Zeng, M.-H.; Chen, X.-M.
CrystEngComm., 2017, 19, 1725−1728.
24)Molecular dynamics of flexible polar cations in a variable confined space: toward exceptional two-step nonlinear optical switches.
Xu, W.-J.; He, C.-T.; Ji, C.-M.; Chen, S.-L.; Huang, R.-K.; Lin, R.-B.; Xue, W.; Luo, J.-H.; Zhang, W.-X.*; Chen, X.-M.
Adv. Mater, 2016, 28, 5886−5890.
25)Structural phase transitions in perovskite compounds based on diatomic or multiatomic bridges.
Xu, W.-J.; Du, Z.-Y.; Zhang, W.-X.*; Chen, X.-M.
CrystEngComm., 2016, 18, 7915−7928.
26)The cation-dependent structural phase transition and dielectric response in a family of cyano-bridged perovskite-like coordination polymers.
Xu, W.-J.; Chen, S.-L.; Hu, Z.-T.; Lin, R.-B.; Su, Y.-J.; Zhang, W.-X.*; Chen, X.-M.*
Dalton Trans., 2016, 45, 4224−4229.
27)Controlling Two-Step Phase Transitions and Dielectric Responses by A-Site Cations in Two Perovskite-like Coordination Polymers.
Xu, W.-J.; Xie, K.-P.; Xiao, Z.-F.; Zhang, W.-X.*; Chen, X.-M.
Cryst. Growth Des., 2016, 16, 7212−7217.
28)Zeolite CAN and AFI-Type ZIFs with large 12-MR pore openings synthesized ssing bulky amides as structure-directing agents.
Shi, Q.; Xu, W.-J.; Huang, R.-K.; Zhang, W.-X.*; Li, Y.; Wang, P.; Shi, F.-N.*; Li, L.; Li, J.; Dong, J.-X.*
J. Am. Chem. Soc., 2016, 138, 16232−16235.
29)Novel porous molybdenum tungsten phosphide hybrid nanosheets on carbon cloth for efficient hydrogen evolution
Wang, X.-D.; Xu, Y.-F.; Rao, H.-S.; Xu, W.-J.; Chen, H.-Y.; Zhang, W.-X.; Kuang, D.-B.*; Su, C.-Y.
Energy Environ. Sci., 2016, 9, 1468−1475.
30)Importing spontaneous polarization into a Heisenberg ferromagnet for a potential single-phase multiferroic.
Huang, B.; Wang, B.-Y.; Du, Z.-Y.; Xue, W.; Xu, W.-J.; Su, Y.-J.; Zhang, W.-X.*; Zeng, M.-H.; Chen, X.-M.
J. Mater. Chem. C, 2016, 4, 8704−8710.
31)Plastic crystals with polar halochromate anion: thermosensitive dielectrics based upon plastic transition and dipole rotation.
Sun, Y.-Z.; Huang, B.; Xu, W.-J.; Zhou, D.-D.; Chen, S.-L.; Zhang, S.-Y.; Du, Z.-Y.*; Xie, Y.-R.; He, C.-T.*; Zhang, W.-X.*; Chen, X.-M.
Inorg. Chem., 2016, 55, 11418−11425.
32)Order-disorder phase transition in the first thiocyanate-bridged double perovskite-type coordination polymer: [NH4]2[NiCd(SCN)6].
Xie, K.-P.; Xu, W.-J.; He, C.-T.; Huang, B.; Du, Z.-Y.; Su, Y.-J.; Zhang, W.-X.*; Chen, X.-M.
CrystEngComm., 2016, 18, 4495−4498.
33)A brilliant cryogenic magnetic coolant: magnetic and magnetocaloric study of ferromagnetically coupled GdF3.
Chen, Y.-C.; Prokleska, J.; Xu, W.-J.; Liu, J.-L.; Liu, J.; Zhang, W.-X.; Jia, J.-H.*; Sechovsky, V.; Tong, M.-L.*
J. Mater. Chem. C, 2015, 3, 12206−12211.
34)Thermal-induced reversible ferroelastic phase transition in a new bromethyl-substituted molecular rotor.
Wang, B. Y.; He, C. T.; Huang, B.; Xu, W. J.; Xue, W.; Du, Z. Y.; Zhang, W.-X.*; Chen, X.-M.
Sci. China Chem., 2015, 58, 1137−1143.
35)Restraining the motion of a ligand for modulating the structural phase transition in two isomorphic polar coordination polymers.
Wang, B.-Y.; Xu, W.-J.; Xue, W.; Lin, R.-B.; Du, Z.-Y.; Zhou, D.-D.; Zhang, W.-X.*; Chen, X.-M.
Dalton Trans., 2014, 43, 9008−9011.
