基本情況
姓名：柯卓鋒(Zhuofeng Ke)
性别：男
出生年月：1980-10
籍貫：廣東
職位：
理學博士。太阳集团app首页“百人計劃”引進人才，副教授，博士生導師。
聯系方式
電話：+86-20-84113071
傳真：暫未填寫
郵箱：kezhf3@mail.sysu.edu.cn
通訊地址：廣州市新港西路135号太阳集团app首页化學與化學工程學院豐盛堂C910
郵編：510275
個人網站：暫未填寫
教育經曆
2005－2009 太阳集团app首页/美國北德克薩斯大學，物理化學，聯合培養博士
2002－2005 太阳集团app首页，高分子化學與物理，碩士
1998－2002 太阳集团app首页，化學系，本科
工作經曆
2016至今 太阳集团app首页，材料科學與工程學院，副教授/博導
2012至今 太阳集团app首页，化學與化學工程學院，副教授/博導
2009－2012 日本京都大學，福井謙一FIFC研究員
講授課程
有機化學、催化化學、有機化學實驗、綜合化學實驗、分子反應動态學等
科研方向
主要研究興趣：理論和實驗相結合，研究分子轉化的新方法與新機理，探索其在有機合成、可再生能源和功能高分子材料領域的應用。
科研項目
廣東省自然科學傑出青年基金，2015.08-2019.08，主持
廣東特支計劃百千萬工程青年拔尖人才，2015.12-2018.12，主持
國家自然科學基金面上項目，2015.01-2018.12，主持
國家自然科學基金青年項目，2013.01-2015.12，主持
太阳集团app首页“百人計劃”啟動項目，2012.4-2013.12，主持
獲獎情況
廣東省自然科學傑出青年(2015)
廣東特支計劃百千萬工程青年拔尖人才(2014)
福井謙一博士後特别研究員基金獎勵（2009-2012）
國家留學基金獎勵（2007）
論著一覽
1. Li, Y., Hou, C., Jiang, J., Zhang, Z., Zhao, C., Page, A., Ke, Zhuofeng*. General H2 Activation Modes for Lewis Acid-Transition Metal Bifunctional Catalysts. ACS Catal. 2016, 6, 1655–1662.
2. Wu J.J, Li Y., Zhou H.Y., Wen A.H., Lun C.C., Yao S.Y., Ke, Zhuofeng*, Ye B.H.*. Copper-Catalyzed Carbamoylation of Terminal Alkynes with Formamides via Cross-Dehydrogenative Coupling. ACS Catal. 2016, 6, 1263–1267.
3. Wei J., Jiang J., Xiao X., Lin D.G.*, Deng Y., Ke, Zhuofeng*, Jiang H.F., Zeng, W*. Copper-Catalyzed Regioselective C-H Sulfonylation of 8-Aminoquinolines. J. Org. Chem. 2016, 81 (3), 946–955.
4. Luo, B.-T., Liu H., Lin Z.-J., Jiang, J., Sheng D.-S., Liu R.-Z., Ke, Zhuofeng*, Liu, F.-S.* Aerobic and Efficient Direct Arylation of Five-Membered Heteroarenes and Their Benzocondensed Derivatives with Aryl Bromides by Bulky α-Hydroxyimine Palladium Complexes. Organometallics, 2015, 34, 4881–4894.
5. Hou, C., Jiang, J., Li, Y., Zhang, Z., Zhao C.*, Ke Zhuofeng*. Unusual Non-bifunctional Mechanism for Co-PNP Complex Catalyzed Transfer Hydrogenation Governed by the Electronic Configuration of Metal Center. Dalton Trans. 2015, 44, 16573–16585.
6. Chung, L. W., Sameera, W. M. C., Ramozzi, R., Page, A. J., Hatanaka, M., Petrova, G. P., Harris, T. V., Li X., Ke, Zhuofeng, Liu, F., Li, H.-B., Ding, L., Morokuma, K.* The ONIOM Method and Its Applications. Chem. Rev. 2015, 15, 5678–5796.
7. Xu, X.-Y., Li, J., Zhang, X., Xu, H., Ke, Zhuo-Feng*, Zhao, C.* Removal of NO with silicene: A DFT investigation. RSC Adv. 2015, 5, 22135–22147.
8. Jiang, J., Hou, C., Zhang S., Luan Z., Zhao, C., Ke, Zhuofeng.* The Effect of HSAB on Stereoselectivity: Copper and Gold Catalyzed 1,3-Phosphatyloxy and 1,3-Halogen Migration Relay to 1,3-Dienes. J. Org. Chem. 2015, 80 (3), 1661–1671.
9. Zhang, F., Fan, J., Yu, H., Ke, Zhuofeng, Nie, C., Kuang, D.*, Shago, G.*, Su C. Nonplanar Organic Sensitizers Featuring a Tetraphenylethene Structure and Double Electron-Withdrawing Anchoring Groups. J. Org. Chem. 2015, 80, 9034–9040.
10. Zhang, M., Zhang, M.-T., Hou, C., Ke, Zhuofeng*, Lu T.-B.* Homogeneous Electrocatalytic Water Oxidation at Neutral pH by a Robust Macrocyclic Nickel(II) Complex. Angew. Chem., Int. Ed. 2014, 53, 13042–13048. (Frontispiece Paper)
11. Hou, C., Jiang J., Zhang S., Wang G., Zhang Z., Ke, Zhuofeng*, Zhao C.* Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect. ACS Catal. 2014, 4, 2990–2997.
12. Zhou, Y.G., Zhang, X.P., Liang, H.Y., Cao, Z.K., Zhao, X.Y., He, Y.W., Wang, S.L., Pang, J.Y., Zhou, Z.Y., Ke, Zhuofeng*, Qiu L.Q.* Enantioselective Synthesis of Axially Chiral Biaryl Monophosphine Oxides via Direct Asymmetric Suzuki Coupling and DFT Investigations of the Enantioselectivity. ACS Catal. 2014, 4, 1390–1397.
13. Petrova, G.P., Ke, Zhuofeng, Park S., Sugiyama H., Morokum K.* The origin of enantioselectivity for intramolecular Friedel–Crafts reaction catalyzed by supramolecular Cu/DNA catalyst complex. Chem. Phys. Lett. 2014, 600, 87–95.
14. Zhang, X., Ke, Zhuofeng, DeYonker N. J., Xu, H., Li Z.-F., Xu X., Zhang X., Su C.-Y., Phillips D. L., Zhao C.* Mechanism and Enantioselectivity of Dirhodium-Catalyzed Intramolecular C–H Amination of Sulfamate. J. Org. Chem. 2013, 78 (24), 12460–12468.
15. Liu, Y., Ma, L., Chen, W.-H.*, Park, H., Ke, Zhuofeng*, Wang, B*. Binding Mechanism and Synergetic Effects of Xanthone Derivatives as Noncompetitive α-Glucosidase Inhibitors: A Theoretical and Experimental Study. J. Phys. Chem. B 2013, 117 (43), 13464–13471.
16. Ye, R.-R., Ke, Zhuofeng, Tan, C.-P., He, L., Ji, L.-N. & Mao, Z.-W. Histone-Deacetylase-Targeted Fluorescent Ruthenium(II) Polypyridyl Complexes as Potent Anticancer Agents. Chem. Eur. J. 2013, 19 (31), 10160 –10169. (Cover Page)
17. Xu, H. Y., Zhang, X. T., Ke, Zhuofeng, Li, Z. F., Xu, X. Y., Su, C. Y., Phillips, D. L. & Zhao, C. Y. Density functional theory study of the mechanism of zinc carbenoid promoted cyclopropanation of allenamides. RSC Adv. 2013, 3, 17131–17142.
18. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. Catalytic Mechanism in Artificial Metalloenzyme: M/MM Study of Phenylacetylene Polymerization by Rhodium Complex Encapsulated in apo-Ferritin. J. Am. Chem. Soc. 2012, 134 (37), 15418–15429.
19. Ke, Zhuofeng, Abe, S., Ueno, T., & Morokuma, Keiji. R-catalyzed Polymerization of Phenylacetylene: Theoretical Studies of the Reaction Mechanism, Regioselectivity and Stereoregularity. J. Am. Chem. Soc. 2011, 133 (20), 7926–7941. (JACS beta Select issue 13)
20. Liu, Y., Ke, Zhuofeng, Liu, Shuwen, Chen, Wen-Hua, Jiang, Shibo; Jiang, Zhi-Hong. An Amphiphilic Conjugate Approach toward the Design and Synthesis of Betulinic Acid-Polyphenol Conjugates as Inhibitors of the HIV-1 gp41 Fusion Core Formation. ChemMedChem 2011, 6 (9), 1654–1664.
21. Gao, H., Ke, Zhuofeng, DeYonker N.J., Wang J., Xu H., Mao Z.-W., Phillips, D.L., Zhao C., Dinuclear Zn(II) Complex Catalyzed Phosphodiester Cleavage Proceeds via a Concerted Mechanism: A Density Functional Theory Study. J. Am. Chem. Soc. 2011, 133 (9), 2904–2915.
22. Ke, Zhuofeng & Cundari, T.R., Palladium-Catalyzed C-H Activation/C-N Bond Formation Reactions: DFT Study of Reaction Mechanisms and Reactive Intermediates. Organometallics 2010, 29 (4), 821–834. (Top10 Most Accessed Articles of Organometallics in 2010)
23. Lee, J.P., Ke, Zhuofeng, Ramirez, M.A., Gunnoe, T.B., Cundari, T.R., Boyle, P.D., & Petersen, J.L., Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones. Organometallics 2009, 28 (6), 1758–1775.
24. Guo, Z., Xue, J.D., Ke, Zhuofeng, Phillips, D.L., & Zhao, C.Y., Influence of Water Hydrogen Bonding on the Reactions of Arylnitrenium Ions With Guanosine: Hydrogen-Bonding Effects Can Favor Reaction at the C8 Site. b>J. Phys. Chem. B 2009, 113 (18), 6528–6532.
25. Foley, N.A., Lee, J.P., Ke, Zhuofeng, Gunnoe, T.B., & Cundari, T.R., Ru(II) Catalysts Supported by Hydridotris(pyrazolyl)borate for the Hydroarylation of Olefins: Reaction Scope, Mechanistic Studies, and Guides for the Development of Improved Catalysts. Acc. Chem. Res. 2009, 42 (5), 585–597.
26. Liu, Y., Ke, Zhuofeng, Cui, J.F., Chen, W.H., Ma, L., & Wang, B., Synthesis, inhibitory activities, and QSAR study of xanthone derivatives as alpha-glucosidase inhibitors. Bioorg. Med. Chem. 2008, 16 (15), 7185-7192.
27. Guo, Z., Ke, Zhuofeng, Phillips, D.L., & Zhao, C.Y., Intrinsic reaction coordinate analysis of the activation of CH4 by molybdenum atoms: A density functional theory study of the crossing seams of the potential energy surfaces. Organometallics 2008, 27 (2), 181–188.
28. Foley, N.A., Ke, Zhuofeng, Gunnoe, T.B., Cundari, T.R., & Petersen, J.L., Aromatic C-H activation and catalytic hydrophenylation of ethylene by TpRu{P(OCH2)(3)CEt}(NCMe)Ph. Organometallics 2008, 27 (13), 3007–3017.
29. Lin, X.F., Zhao, C.Y., Che, C.M., Ke, Zhuofeng, & Phillips, D.L., A DFT study on the mechanism of Rh-2(II,II)-catalyzed intramolecular amidation of carbamates. Chem. Asian J. 2007, 2 (9), 1101–1108.
30. Ke, Zhuofeng, Zhou, Y.B., Gao, H., Zhao, C.Y., & Phillips, D.L., On the mechanism and stereochemistry of chiral lithium-carbenoid-promoted cyclopropanation reactions. Chem. Eur. J. 2007, 13 (23), 6724–6731.
31. Ke, Zhuofeng, Zhao, C.Y., & Phillips, D.L., Methylene transfer or carbometalation? A theoretical study to determine the mechanism of lithium carbenoid-promoted cyclopropanation reactions in aggregation and solvation states. J. Org. Chem. 2007, 72 (3), 848–860.
32. Gao, H.Y., Ke, Zhuofeng, Pei, L.X., Song, K.M., & Wu, Q., Drastic ligand electronic effect on anilido-imino nickel catalysts toward ethylene polymerization. Polymer 2007, 48 (25), 7249–7254.
33. Fang, R., Ke, Zhuofeng, Shen, Y., Zhao, C.Y., & Phillips, D.L., Concurrent cyclopropanation by carbenes and carbanions? A density functional theory study on the reaction pathways. J. Org. Chem. 2007, 72 (14), 5139–5145.
34. Zhou, Y.B., Ke, Zhuofeng, & Zhao, C.Y., A theoretical study on the mechanism of ruthenium(II)-catalyzed reaction of organic azide with alkyne. Acta Chim. Sin. 2006, 64 (20), 2071–2078.
35. Zhang, J.K., Ke, Zhuofeng, Bao, F., Long, J.M., Gao, H.Y., Zhu, F.M., & Wu, Q., Ethylene polymerization and oligomerization catalyzed by bulky beta-diketiminato Ni(II) and beta-diimine Ni(II) complexes/methylaluminoxane systems. J. Mol. Catal. A: Chem 2006, 249 (1-2), 31–39.
36. Ye, G.D., Ke, Zhuofeng, Yan, J.W., Zhao, T.Y., Zeng, Z.H., & Chen, Y.L., Low VOC bifunctional photoinitiator based on alpha-hydroxyalkylphenone structure. Polymer 2006, 47 (13), 4603–4612.
37. Li, Z.H., Ke, Zhuofeng, Zhao, C.Y., Geng, Z.Y., Wang, Y.C., & Phillips, D.L., A density functional theory study of aluminum carbenoid (CH3)(2)AlCH2X (X = Cl, Br, I) promoted cyclopropanation reactions compared to IMCH2I (M = Li, Sm, Zn) carbenoids. Organometallics 2006, 25 (15), 3735–3742.
38. Zhang, J.K., Gao, H.Y., Ke, Zhuofeng, Bao, F., Zhu, F.M., & Wu, Q., Investigation of 1-hexene isomerization and oligomerization catalyzed with beta-diketiminato Ni(II) bromide complexes/methylaluminoxane system. J. Mol. Catal. A: Chem2006, 231 (1-2), 27–34.
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